Viewtiful Joe: Red Hot Rumble

Play as Charles the Third:
Complete any story mode chapter with any two characters.

Play as Dark Hero Jet Black:
Complete Boss*Boss*Bang*Bang in story mode.
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Play as Director Blue:
Complete Gulliver's Battles Special Edition in story mode.

Play as Fighter Bianky and Friends:
Complete Red Hot Rumble in story mode.

Play as Gran Bruce:
Complete any chapter in story mode with any four characters.

Play as Heroine Silvia:
Complete Viewtiful Cartoon World Special Edition in story mode.

Play as Hulk Davidson:
Complete any chapter in story mode with any three characters.

Play as Manager Jet:
Complete Atlantis: Four Adventures of the Sea Special Edition in story mode.

Play as Movie Fan Joe:
Complete Captain Blue Begins Special Edition in story mode.

Play as Rachel:
Complete Les Acteurs Incroyable in story mode.

Play as Sprocket:
Complete any chapter in story mode with any character.

Play as Stylish Alastor:
Complete Riddle of the Incan Empire! Special Edition in story mode,

Play as Young Blue Jr.:
Complete Truth of the Black Film Special Edition in story mode.

Play as Young Captain Blue:
Complete The Hidden Hideout in story mode.

Alternate costumes:
Complete all the V-Puzzles to unlock the "EX Color" option at the character selection screen. Highlight a character and press X to choose the EX version of their costume.

To unlock the EX color for all characters, complete 500 multi-player battles.

Bonus Battle Mode stages:
Complete the indicated story mode levels to unlock the corresponding bonus stage in Battle Mode. Press Y or X on the stage to choose it after it has been unlocked..

Stage 1 Special Edition: Riddle of the Incan Empire - Special Edition
Stage 1-B (Treasure Guardian Vircachoca): Riddle of the Incan Empire
Stage 2 Special Edition: Viewtiful Cartoon World - Special Edition
Stage 2-B (Hulk Davidson is in Town!): Viewtiful Cartoon World
Stage 3 Special Edition: Captain Blue Begins - Special Edition
Stage 3-B (Super Brothers): Captain Blue Begins
Stage 4 Special Edition: The Truth of the Black Film - Special Edition
Stage 4-1 (Emergency Plant): The Truth of the Black Film
Stage 4-2 (Big Bad Burnin' Buddha): The Truth of the Black Film
Stage 4-3 (The Dino): The Truth of the Black Film
Stage 4-B (Bouncer): The Truth of the Black Film
Stage 5 Special Edition: Gulliver's Battles - Special Edition
Stage 5-1 (To the Heavens...): Gulliver's Battles
Stage 5-2 (The Secret Sky Garden): Gulliver's Battles
Stage 5-3 (Clockwork Catastrophe): Gulliver's Battles
Stage 5-4 (Spider-Machine): Gulliver's Battles
Stage 6 Special Edition: Atlantis: Four Adventures of the Sea - Special Edition
Stage 6-1 (20,000,000 Leagues Under the Sea): Atlantis: Four Adventures of the Sea
Stage 6-2 (The Search for Red Hot Rumble): Atlantis: Four Adventures of the Sea
Stage 6-3 (The Secret Temple of Atlantis): Atlantis: Four Adventures of the Sea
Stage 6-B (Poseidon Avenger): Atlantis: Four Adventures of the Sea
Stage 7 Special Edition: Boss*Boss*Bang*Bang
Stage 7-B (Les Acteurs Incroyable): Les Acteurs Incroyable

Movies:
Complete the indicated story mode chapter to unlock the corresponding movie.

Atlantis: Four Adventures of the Sea: Gulliver's Battles
Atlantis: Four Adventures of the Sea Special Edition: V-Puzzle 6
Boss*Boss*Bang*Bang: All previous chapters except The Hidden Hideout
Captain Blue Begins: Viewtiful Cartoon World
Captain Blue Begins Special Edition: V-Puzzle 3
Gulliver's Battles: Truth of the Black Film
Gulliver's Battles Special Edition: V-Puzzle 5
Les Acteurs Incroyable: Atlantis: Four Adventures of the Sea
Red Hot Rumble: Boss*Boss*Bang*Bang
Riddle of the Incan Empire! Special Edition: V-Puzzle 1
The Hidden Hideout: Any chapter with Charles the Third, Hulk Davidson, and Gran Bruce
Truth of the Black Film: Captain Blue Begins
Truth of the Black Film Special Edition: V-Puzzle 4
Viewtiful Cartoon World: Riddle of the Incan Empire!
Viewtiful Cartoon World Special Edition: V-Puzzle 2
Ending Movie: Les Acteurs Incroyable
Last Battle Intro Movie: Les Acteurs Incroyable
Opening Movie: Riddle of the Incan Empire!

Anime Concept Art:
Complete the indicated story mode chapter to unlock the corresponding artwork.

Concept Art 1: Jadow Stars: V-Puzzle 7
Concept Art 2: Jadow Villains: V-Puzzle 8
Concept Art 3: Gedow Stars: V-Puzzle 9
Concept Art 4: Gedow Villains: V-Puzzle 10
Concept Art 5: Main Villains: V-Puzzle 11
Concept Art 6: Main Stars: V-Puzzle 12